MIT Devises New Effecient Way to Remove Contaminants From Nuclear Wastewater
Science & Technology

MIT Devises New Effecient Way to Remove Contaminants From Nuclear Wastewater

A small-scale gadget, seen right here, was used within the lab to reveal the effectiveness of the brand new shockwave-based system for eradicating radioactive contaminants from the cooling water in nuclear powerplants. Credit score: Picture courtesy of the researchers

Nuclear energy continues to increase globally, propelled, partially, by the truth that it produces few greenhouse fuel emissions whereas offering regular energy output. However together with that enlargement comes an elevated want for coping with the massive volumes of water used for cooling these vegetation, which turns into contaminated with radioactive isotopes that require particular long-term disposal.

Now, a technique developed at MIT gives a manner of considerably decreasing the quantity of contaminated water that wants to be disposed of, as an alternative concentrating the contaminants and permitting the remainder of the water to be recycled by way of the plant’s cooling system. The proposed system is described within the journal Environmental Science and Expertise, in a paper by graduate pupil Mohammad Alkhadra, professor of chemical engineering Martin Bazant, and three others.

The tactic makes use of a course of known as shock electrodialysis, which makes use of an electrical discipline to generate a deionization shockwave within the water. The shockwave pushes the electrically charged particles, or ions, to one facet of a tube full of charged porous materials, in order that concentrated stream of contaminants may be separated out from the remainder of the water. The group found that two radionuclide contaminants — isotopes of cobalt and cesium — may be selectively faraway from water that additionally incorporates boric acid and lithium. After the water stream is cleansed of its cobalt and cesium contaminants, it may be reused within the reactor.

Diagram illustrates the method, wherein contaminated water enters from the left, and is subjected to an ionic shockwave (depicted by dashed purple strains) that concentrates radionuclides of cesium and cobalt on one facet (darker space at prime) from purified water (light-colored decrease space). The clear water may be recirculated to the reactor, whereas the concentrated contaminants may be safely disposed of. Credit score: Picture courtesy of the researchers

The shock electrodialysis course of was initially developed by Bazant and his co-workers as a normal technique of eradicating salt from water, as demonstrated of their first scalable prototype 4 years in the past. Now, the staff has centered on this extra particular utility, which may assist enhance the economics and environmental affect of working nuclear energy vegetation. In ongoing analysis, they’re additionally persevering with to develop a system for eradicating different contaminants, together with lead, from ingesting water.

Not solely is the brand new system cheap and scalable to giant sizes, however in precept, it can also cope with a variety of contaminants, Bazant says. “It’s a single gadget that may carry out an entire vary of separations for any particular utility,” he says.

Of their earlier desalination work, the researchers used measurements of the water’s electrical conductivity to decide how a lot salt was eliminated. Within the years since then, the staff has developed different strategies for detecting and quantifying the main points of what’s within the concentrated radioactive waste and the cleaned water.

“We rigorously measure the composition of all of the stuff going out and in,” says Bazant, who’s the E.G. Roos Professor of Chemical Engineering in addition to a professor of arithmetic. “This actually opened up a brand new path for our analysis.” They started to give attention to separation processes that might be helpful for well being causes or that might lead to concentrating materials that has excessive worth, both for reuse or to offset disposal prices.

The tactic they developed works for sea water desalination, however it’s a comparatively energy-intensive course of for that utility. The power price is dramatically decrease when the tactic is used for ion-selective separations from dilute streams comparable to nuclear plant cooling water. For this utility, which additionally requires costly disposal, the tactic makes financial sense, he says. It additionally hits each of the staff’s targets: coping with high-value supplies and serving to to safeguard well being. The size of the appliance can also be vital — a single giant nuclear plant can flow into about 10 million cubic meters of water per yr by way of its cooling system, Alkhadra says.

For his or her checks of the system, the researchers used simulated nuclear wastewater based mostly on a recipe offered by Mitsubishi Heavy Industries, which sponsored the analysis and is a significant builder of nuclear vegetation. Within the staff’s checks, after a three-stage separation course of, they had been in a position to take away 99.5 p.c of the cobalt radionuclides within the water whereas retaining about 43 p.c of the water in cleaned-up type in order that it might be reused. As a lot as two-thirds of the water may be reused if the cleanup degree is in the reduction of to 98.3 p.c of the contaminants eliminated, the staff discovered.

Whereas the general technique has many potential purposes, the nuclear wastewater separation, is “one of many first issues we expect we are able to resolve [with this method] that no different resolution exists for,” Bazant says. No different sensible, steady, financial technique has been discovered for separating out the radioactive isotopes of cobalt and cesium, the 2 main contaminants of nuclear wastewater, he provides.

Whereas the tactic might be used for routine cleanup, it may additionally make an enormous distinction in coping with extra excessive instances, such because the thousands and thousands of gallons of contaminated water on the broken Fukushima Daichi energy plant in Japan, the place the buildup of that contaminated water has threatened to overpower the containment methods designed to forestall it from leaking out into the adjoining Pacific. Whereas the brand new system has to date solely been examined at a lot smaller scales, Bazant says that such large-scale decontamination methods based mostly on this technique may be doable “inside just a few years.”

The analysis staff additionally included MIT postdocs Kameron Conforti and Tao Gao and graduate pupil Huanhuan Tian.

Reference: “Steady Separation of Radionuclides from Contaminated Water by Shock Electrodialysis” by Mohammad A. Alkhadra, Kameron M. Conforti, Tao Gao, Huanhuan Tian and Martin Z. Bazant, 3 December 2019, Environmental Science and Expertise.
DOI: 10.1021/acs.est.9b05380

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