The involvement between electron switch (ET) and catalytic response at electrocatalyst floor makes electrochemical course of difficult to know and management. How one can experimentally decide ET course of occurring at nanoscale is essential to know the general electrochemical response course of at energetic websites.
Lately, a analysis group led by Prof. LI Can and Prof. FAN Fengtao from the Dalian Institute of Chemical Physics (DICP) of the Chinese language Academy of Sciences (CAS) captured the electron switch imaging in electrocatalysis course of.
This examine was lately revealed in the journal Nano Letters.
The researchers established an in-situ electrochemical imaging methodology with nanoscale spatial decision, which mixed atomic pressure microscopy and scanning electrochemical imaging. This methodology can notice the three-dimensional motion of the scanning nanoprobe to map the native distribution of the generated outer-spherical electron switch molecules and the catalytic product molecules.
The visible electron switch photos on metallic nanoplates straight demonstrated that the electron switch course of at nanoscale introduced a site-dependent heterogeneity.
Furthermore, to decouple the interference of the mass switch impact on the electron switch, the researchers carried out a collection of elaborate experiments and complicated mathematical modeling to extract the speed fixed and inner potential distinction. They discovered that the connection between the interfacial inside potential distinction and the speed fixed adopted a linear vogue.
This work realizes the in-situ statement of electron switch course of and catalytic response in the electrochemical response, and gives new concepts for the event of in-situ imaging characterization methodology and the detection of the mechanism of the electrocatalytic reactions.
“It is a new milestone of the scanning electrochemical probe methods, making it doable to find the structure-performance relation of nanocatalyst from the underside of bodily and chemical rules,” commented by one of many reviewers.
Reference: “Visualizing the Spatial Heterogeneity of Electron Transfer on a Metallic Nanoplate Prism” by Wei Nie, Qianhong Zhu, Yuying Gao, Ziyuan Wang, Yong Liu, Xun Wang, Ruotian Chen, Fengtao Fan and Can Li, 14 October 2021, Nano Letters.